Single-Molecule Force Spectroscopy on Poly(acrylic acid) by AFM

نویسندگان

  • Hongbin Li
  • Bingbing Liu
  • Xi Zhang
  • Chunxiao Gao
  • Jiacong Shen
  • Guangtian Zou
چکیده

The mechanical properties of poly(acrylic acid) (PAA) were investigated on the molecular scale by using AFM. PAA was adsorbed onto a glass substrate and then picked up at one point of the chain with the AFM tip and stretched. The deformation of single PAA chains under tension was measured and modeled by a modified freely-joint-chain model. The length distribution of loops and tails of adsorbed PAA on the glass substrate was also studied by analyzing the extension of the filaments.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Nanoparticles of Block Ionomer Complexes from Double Hydrophilic Poly(acrylic acid)-b-poly(ethylene oxide)-b-poly(acrylic acid) Triblock Copolymer and Oppositely Charged Surfactant

The novel water-dispersible nanoparticles from the double hydrophilic poly(acrylic acid)-b-poly(ethylene oxide)-b-poly(acrylic acid) (PAA-b-PEO-b-PAA) triblock copolymer and oppositely charged surfactant dodecyltrimethyl ammonium bromide (DTAB) were prepared by mixing the individual aqueous solutions. The structure of the nanoparticles was investigated as a function of the degree of neutralizat...

متن کامل

Investigating single molecule adhesion by atomic force spectroscopy.

Atomic force spectroscopy is an ideal tool to study molecules at surfaces and interfaces. An experimental protocol to couple a large variety of single molecules covalently onto an AFM tip is presented. At the same time the AFM tip is passivated to prevent unspecific interactions between the tip and the substrate, which is a prerequisite to study single molecules attached to the AFM tip. Analyse...

متن کامل

Single-molecule force spectroscopy of supramolecular heterodimeric capsules.

The specific interaction of a supramolecular binding motif was quantitatively evaluated by dynamic single-molecule force spectroscopy (SMFS) using an atomic force microscope (AFM). The supramolecular capsule forms by two different cavitands stitched together by four hydrogen bonds between carboxylic acid and pyridyl groups. The tetra(carboxyl)cavitand is monofunctionalized at the lower rim with...

متن کامل

Entropic Elasticity of Single Polymer Chains of Poly(methacrylic acid) Measured by Atomic Force Microscopy

We have directly measured the entropic elasticity due to the uncoiling of individual polymer chains of poly(methacrylic acid) (PMAA) using the atomic force microscope (AFM). Covalent attachment of one chain end to a substrate and sufficiently low chain grafting densities were achieved by using a mixed monolayer technique that involved the co-chemisorption of (mono)thiol-functionalized PMAA and ...

متن کامل

Revisiting atomic force microscopy force spectroscopy sensitivity for single molecule studies

Recently, the rapid advances in quantitative biology and polymer science have led to the atomic force microscope AFM being extensively employed for single-molecule force spectroscopy. Deflection sensitivity, a critical factor in single molecule force spectroscopy, is changed due to the change in bending shape of AFM cantilever when a single molecule is attached to the AFM cantilever tip. We qua...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1999